{ "document_id": 14408, "page": 17, "width_pt": 612, "height_pt": 792, "rotation": 0, "pipeline_version": "paddleocr-vl-1.6+paul-48", "engine": "paddleocr_vl", "source_run_id": 14519, "item_count": 192, "counts_by_type": { "footnote": 1, "formula": 8, "header": 5, "table": 4, "table_cell": 151, "text": 23 }, "build_ms": 32, "items": [ { "id": "p17.1", "order": 1, "type": "header", "bbox": { "l": 53.52, "t": 765.6, "r": 71.04, "b": 756.96 }, "text": "520", "attrs": { "block_label": "number" }, "level": 2 }, { "id": "p17.2", "order": 2, "type": "header", "bbox": { "l": 75.6, "t": 766.08, "r": 264.24, "b": 756.24 }, "text": "Journal of Natural Products, 1999, Vol. 62, No. 3", "attrs": { "block_label": "header" }, "level": 2 }, { "id": "p17.3", "order": 3, "type": "header", "bbox": { "l": 501.12, "t": 766.08, "r": 559.68, "b": 756 }, "text": "Invited Review", "attrs": { "block_label": "header" }, "level": 2 }, { "id": "p17.4", "order": 4, "type": "header", "bbox": { "l": 53.28, "t": 746.16, "r": 142.8, "b": 736.08 }, "text": "Table 4. (Continued)", "attrs": { "block_label": "figure_title" }, "level": 2 }, { "id": "p17.5", "order": 5, "type": "header", "bbox": { "l": 236.64, "t": 734.4, "r": 374.16, "b": 724.32 }, "text": "Mono-THF Acetogenins (Continued)", "attrs": { "block_label": "figure_title" }, "level": 2 }, { "id": "p17.6", "order": 6, "type": "text", "bbox": { "l": 62.16, "t": 726, "r": 203.04, "b": 715.2 }, "text": "38. glabranin[p17.6.1] (C [p17.6.2]H [p17.6.3]O[p17.6.4], MW622)", "children": [ { "id": "p17.6.1", "order": 7, "type": "text", "bbox": { "l": 62.16, "t": 726, "r": 203.04, "b": 715.2 }, "text": "²³", "attrs": { "inline": true, "text_offset": 13, "text_span": 9, "bbox_estimated": true } }, { "id": "p17.6.2", "order": 8, "type": "text", "bbox": { "l": 62.16, "t": 726, "r": 203.04, "b": 715.2 }, "text": "₃₇", "attrs": { "inline": true, "text_offset": 26, "text_span": 9, "bbox_estimated": true } }, { "id": "p17.6.3", "order": 9, "type": "text", "bbox": { "l": 62.16, "t": 726, "r": 203.04, "b": 715.2 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"text": "19", "attrs": { "row": 0, "col": 4, "rowspan": 1, "colspan": 1, "column_header": true, "header_source": "heuristic" } }, { "id": "p17.8.6", "order": 18, "type": "table_cell", "bbox": { "l": 322.59, "t": 659.76, "r": 356.34, "b": 647.76 }, "text": "20", "attrs": { "row": 0, "col": 5, "rowspan": 1, "colspan": 1, "column_header": true, "header_source": "heuristic" } }, { "id": "p17.8.7", "order": 19, "type": "table_cell", "bbox": { "l": 356.34, "t": 659.76, "r": 390.09, "b": 647.76 }, "text": "23", "attrs": { "row": 0, "col": 6, "rowspan": 1, "colspan": 1, "column_header": true, "header_source": "heuristic" } }, { "id": "p17.8.8", "order": 20, "type": "table_cell", "bbox": { "l": 390.09, "t": 659.76, "r": 423.84, "b": 647.76 }, "text": "24", "attrs": { "row": 0, "col": 7, "rowspan": 1, "colspan": 1, "column_header": true, "header_source": "heuristic" } }, { "id": "p17.8.9", "order": 21, "type": "table_cell", "bbox": { "l": 153.84, "t": 647.76, "r": 187.59, "b": 635.76 }, "text": 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"attrs": { "row": 1, "col": 5, "rowspan": 1, "colspan": 1 } }, { "id": "p17.8.15", "order": 27, "type": "table_cell", "bbox": { "l": 356.34, "t": 647.76, "r": 390.09, "b": 635.76 }, "text": "5.35", "attrs": { "row": 1, "col": 6, "rowspan": 1, "colspan": 1 } }, { "id": "p17.8.16", "order": 28, "type": "table_cell", "bbox": { "l": 390.09, "t": 647.76, "r": 423.84, "b": 635.76 }, "text": "5.38", "attrs": { "row": 1, "col": 7, "rowspan": 1, "colspan": 1 } }, { "id": "p17.8.17", "order": 29, "type": "table_cell", "bbox": { "l": 153.84, "t": 635.76, "r": 187.59, "b": 623.76 }, "text": "¹³C ( δ)", "attrs": { "row": 2, "col": 0, "rowspan": 1, "colspan": 1 } }, { "id": "p17.8.18", "order": 30, "type": "table_cell", "bbox": { "l": 187.59, "t": 635.76, "r": 221.34, "b": 623.76 }, "text": "79.31", "attrs": { "row": 2, "col": 1, "rowspan": 1, "colspan": 1 } }, { "id": "p17.8.19", "order": 31, "type": "table_cell", "bbox": { "l": 221.34, "t": 635.76, "r": 255.09, "b": 623.76 }, "text": "81.72", "attrs": { "row": 2, "col": 2, "rowspan": 1, "colspan": 1 } }, { "id": "p17.8.20", "order": 32, "type": "table_cell", "bbox": { "l": 255.09, "t": 635.76, "r": 288.84, "b": 623.76 }, "text": "74.42", "attrs": { "row": 2, "col": 3, "rowspan": 1, "colspan": 1 } }, { "id": "p17.8.21", "order": 33, "type": "table_cell", "bbox": { "l": 288.84, "t": 635.76, "r": 322.59, "b": 623.76 }, "text": "74.23", "attrs": { "row": 2, "col": 4, "rowspan": 1, "colspan": 1 } }, { "id": "p17.8.22", "order": 34, "type": "table_cell", "bbox": { "l": 322.59, "t": 635.76, "r": 356.34, "b": 623.76 }, "text": "74.59", "attrs": { "row": 2, "col": 5, "rowspan": 1, "colspan": 1 } }, { "id": "p17.8.23", "order": 35, "type": "table_cell", "bbox": { "l": 356.34, "t": 635.76, "r": 390.09, "b": 623.76 }, "text": "128.60", "attrs": { "row": 2, "col": 6, "rowspan": 1, "colspan": 1 } }, { "id": "p17.8.24", "order": 36, "type": "table_cell", "bbox": { "l": 390.09, "t": 635.76, "r": 423.84, "b": 623.76 }, "text": "130.18", "attrs": { "row": 2, "col": 7, "rowspan": 1, "colspan": 1 } } ] }, { "id": "p17.9", "order": 37, "type": "text", "bbox": { "l": 62.16, "t": 623.28, "r": 529.2, "b": 593.52 }, "text": "Amorphous powder. MS: EIMS m/z 493, 475, 379, 361, 309, 295, 293, 291, 269, 267, 251, 249, 225. NMR: [p17.9.1]H NMR (400 MHz, CDCl[p17.9.2]), [p17.9.3]C NMR (100 MHz, CDCl[p17.9.4]). Derivatives: peracetate (1H NMR). Source: Annona glabra, seeds.\n\ngoniodonin[p17.9.5] (reported as an epimeric pair) (C [p17.9.6]H [p17.9.7]O[p17.9.8], MW612)", "children": [ { "id": "p17.9.1", "order": 38, "type": "formula", "bbox": { "l": 62.16, "t": 623.28, "r": 529.2, "b": 593.52 }, "text": "¹", "attrs": { "latex": "^{1}", "inline": true, "text_offset": 101, "text_span": 9, "bbox_estimated": true, "alt": "to the power of 1", "mathml": "1" } }, { "id": "p17.9.2", "order": 39, "type": "text", "bbox": { "l": 62.16, "t": 623.28, "r": 529.2, "b": 593.52 }, "text": "₃", "attrs": { "inline": true, "text_offset": 130, "text_span": 9, "bbox_estimated": true } }, { "id": "p17.9.3", "order": 40, "type": "formula", "bbox": { "l": 62.16, "t": 623.28, "r": 529.2, "b": 593.52 }, "text": "¹³", "attrs": { "latex": "^{13}", "inline": true, "text_offset": 142, "text_span": 9, "bbox_estimated": true, "alt": "to the power of 13", "mathml": "13" } }, { "id": "p17.9.4", "order": 41, "type": "text", "bbox": { "l": 62.16, "t": 623.28, 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"id": "p17.10", "order": 46, "type": "formula", "bbox": { "l": 154.32, "t": 593.04, "r": 456.48, "b": 546.24 }, "text": "", "attrs": { "block_label": "image", "alt": "Skeletal structure of an annonaceous acetogenin: butenolide with hydroxyls at C-4, C-10, C-15, C-20 and a bis-THF ring, long…", "source": "vision" } }, { "id": "p17.11", "order": 47, "type": "text", "bbox": { "l": 62.88, "t": 544.56, "r": 127.2, "b": 534.48 }, "text": "39. goniodon" }, { "id": "p17.12", "order": 48, "type": "table", "bbox": { "l": 189.84, "t": 534.48, "r": 421.68, "b": 441.077873 }, "text": "", "attrs": { "block_label": "table", "n_rows": 6, "n_cols": 7, "integrity": { "cells_checked": 40, "cells_flagged": 39, "flags": [ { "row": 0, "col": 0, "coverage": 0, "text": "Position" }, { "row": 0, "col": 1, "coverage": 0, "text": "10" }, { "row": 0, "col": 2, "coverage": 0, "text": "15" }, { "row": 0, "col": 3, "coverage": 0, "text": "16" }, { "row": 0, "col": 4, "coverage": 0, "text": "19" }, { "row": 0, "col": 5, "coverage": 0, "text": "20" }, { "row": 1, "col": 0, "coverage": 0, "text": "¹H ( δ)" }, { "row": 1, "col": 1, "coverage": 0, "text": "3.63 m" }, { "row": 1, "col": 2, "coverage": 0, "text": "3.41 m" }, { "row": 1, "col": 3, "coverage": 0, "text": "3.78 m" }, { "row": 1, "col": 4, "coverage": 0, "text": "3.78 m" }, { "row": 1, "col": 5, "coverage": 0, "text": "3.41 m" } ] } }, "children": [ { "id": "p17.12.1", "order": 49, "type": "table_cell", "bbox": { "l": 189.84, "t": 534.48, "r": 222.96, "b": 520.84 }, "text": "Position", "attrs": { "row": 0, "col": 0, "rowspan": 1, "colspan": 1, "column_header": true, "header_source": "heuristic" } }, { "id": "p17.12.2", "order": 50, "type": "table_cell", "bbox": { "l": 222.96, "t": 534.48, "r": 256.08, "b": 520.84 }, "text": "10", "attrs": { "row": 0, "col": 1, "rowspan": 1, "colspan": 1, "column_header": true, "header_source": "heuristic" } }, { "id": "p17.12.3", "order": 51, "type": "table_cell", "bbox": { "l": 256.08, "t": 534.48, "r": 289.2, "b": 520.84 }, "text": "15", "attrs": { "row": 0, "col": 2, "rowspan": 1, "colspan": 1, "column_header": true, "header_source": "heuristic" } }, { "id": "p17.12.4", "order": 52, "type": "table_cell", "bbox": { "l": 289.2, "t": 534.48, "r": 322.32, "b": 520.84 }, "text": "16", "attrs": { "row": 0, "col": 3, "rowspan": 1, "colspan": 1, "column_header": true, "header_source": "heuristic" } }, { "id": "p17.12.5", "order": 53, "type": "table_cell", "bbox": { "l": 322.32, "t": 534.48, "r": 355.44, "b": 520.84 }, "text": "19", "attrs": { "row": 0, "col": 4, "rowspan": 1, "colspan": 1, "column_header": true, "header_source": "heuristic" } }, { "id": "p17.12.6", "order": 54, "type": "table_cell", "bbox": { "l": 355.44, "t": 534.48, "r": 388.56, "b": 520.84 }, "text": "20", "attrs": { "row": 0, "col": 5, "rowspan": 1, "colspan": 1, "column_header": true, "header_source": "heuristic" } }, { "id": "p17.12.7", "order": 55, "type": "table_cell", "bbox": { "l": 249.88488, "t": 456.43997, "r": 264.160984, "b": 441.077873 }, "text": "34", "attrs": { "row": 0, "col": 6, "rowspan": 1, "colspan": 1, "bbox_refit": true, "column_header": true, "header_source": "heuristic" } }, { "id": "p17.12.8", "order": 56, "type": "table_cell", "bbox": { "l": 189.84, "t": 520.84, "r": 222.96, "b": 507.2 }, "text": "¹H ( δ)", "attrs": { "row": 1, "col": 0, "rowspan": 1, "colspan": 1 } }, { "id": "p17.12.9", "order": 57, "type": "table_cell", "bbox": { "l": 222.96, "t": 520.84, "r": 256.08, "b": 507.2 }, "text": "3.63 m", "attrs": { "row": 1, "col": 1, "rowspan": 1, "colspan": 1 } }, { "id": "p17.12.10", "order": 58, "type": "table_cell", "bbox": { "l": 256.08, "t": 520.84, "r": 289.2, "b": 507.2 }, "text": "3.41 m", "attrs": { "row": 1, "col": 2, "rowspan": 1, "colspan": 1 } }, { "id": "p17.12.11", "order": 59, "type": "table_cell", "bbox": { "l": 289.2, "t": 520.84, "r": 322.32, "b": 507.2 }, "text": "3.78 m", "attrs": { "row": 1, "col": 3, "rowspan": 1, "colspan": 1 } }, { "id": "p17.12.12", "order": 60, "type": "table_cell", "bbox": { "l": 322.32, "t": 520.84, "r": 355.44, "b": 507.2 }, "text": "3.78 m", "attrs": { "row": 1, "col": 4, "rowspan": 1, "colspan": 1 } }, { "id": "p17.12.13", "order": 61, "type": "table_cell", "bbox": { "l": 355.44, "t": 520.84, "r": 388.56, "b": 507.2 }, "text": "3.41 m", "attrs": { "row": 1, "col": 5, "rowspan": 1, "colspan": 1 } }, { "id": "p17.12.14", "order": 62, "type": "table_cell", "bbox": { "l": 388.56, "t": 520.84, "r": 421.68, "b": 507.2 }, "text": "---", "attrs": { "row": 1, "col": 6, "rowspan": 1, "colspan": 1 } }, { "id": "p17.12.15", "order": 63, "type": "table_cell", "bbox": { "l": 189.84, "t": 507.2, "r": 222.96, "b": 493.56 }, "text": "¹³C ( δ)", "attrs": { "row": 2, "col": 0, "rowspan": 1, "colspan": 1 } }, { "id": "p17.12.16", "order": 64, "type": "table_cell", "bbox": { "l": 222.96, "t": 507.2, "r": 256.08, "b": 493.56 }, "text": "71.5", "attrs": { "row": 2, "col": 1, "rowspan": 1, "colspan": 1 } }, { "id": "p17.12.17", "order": 65, "type": "table_cell", "bbox": { "l": 256.08, "t": 507.2, "r": 289.2, "b": 493.56 }, "text": "74.4", "attrs": { "row": 2, "col": 2, "rowspan": 1, "colspan": 1 } }, { "id": "p17.12.18", "order": 66, "type": "table_cell", "bbox": { "l": 289.2, "t": 507.2, "r": 322.32, "b": 493.56 }, "text": "82.5", "attrs": { "row": 2, "col": 3, "rowspan": 1, "colspan": 1 } }, { "id": "p17.12.19", "order": 67, "type": "table_cell", "bbox": { "l": 322.32, "t": 507.2, "r": 355.44, "b": 493.56 }, "text": "82.7", "attrs": { "row": 2, "col": 4, "rowspan": 1, "colspan": 1 } }, { "id": "p17.12.20", "order": 68, "type": "table_cell", "bbox": { "l": 355.44, "t": 507.2, "r": 388.56, "b": 493.56 }, "text": "74.3", "attrs": { "row": 2, "col": 5, "rowspan": 1, "colspan": 1 } }, { "id": "p17.12.21", "order": 69, "type": "table_cell", "bbox": { "l": 388.56, "t": 507.2, "r": 421.68, "b": 493.56 }, "text": "105.0", "attrs": { "row": 2, "col": 6, "rowspan": 1, "colspan": 1 } }, { "id": "p17.12.22", "order": 70, "type": "table_cell", "bbox": { "l": 189.84, "t": 493.56, "r": 222.96, "b": 479.92 }, "text": "Position", "attrs": { "row": 3, "col": 0, "rowspan": 1, "colspan": 1 } }, { "id": "p17.12.23", "order": 71, "type": "table_cell", "bbox": { "l": 222.96, "t": 493.56, "r": 256.08, "b": 479.92 }, "text": "10", "attrs": { "row": 3, "col": 1, "rowspan": 1, "colspan": 1 } }, { "id": "p17.12.24", "order": 72, "type": "table_cell", "bbox": { "l": 256.08, "t": 493.56, "r": 289.2, "b": 479.92 }, "text": "15", "attrs": { "row": 3, "col": 2, "rowspan": 1, "colspan": 1 } }, { "id": "p17.12.25", "order": 73, "type": "table_cell", "bbox": { "l": 289.2, "t": 493.56, "r": 322.32, "b": 479.92 }, "text": "16", "attrs": { "row": 3, "col": 3, "rowspan": 1, "colspan": 1 } }, { "id": "p17.12.26", "order": 74, "type": "table_cell", "bbox": { "l": 322.32, "t": 493.56, "r": 355.44, "b": 479.92 }, "text": "19", "attrs": { "row": 3, "col": 4, "rowspan": 1, "colspan": 1 } }, { "id": "p17.12.27", "order": 75, "type": "table_cell", "bbox": { "l": 355.44, "t": 493.56, "r": 388.56, "b": 479.92 }, "text": "20", "attrs": { "row": 3, "col": 5, "rowspan": 1, "colspan": 1 } }, { "id": "p17.12.28", "order": 76, "type": "table_cell", "bbox": { "l": 388.56, "t": 493.56, "r": 421.68, "b": 479.92 }, "text": "34", "attrs": { "row": 3, "col": 6, "rowspan": 1, "colspan": 1 } }, { "id": "p17.12.29", "order": 77, "type": "table_cell", "bbox": { "l": 189.84, "t": 479.92, "r": 222.96, "b": 466.28 }, "text": "¹H ( δ)", "attrs": { "row": 4, "col": 0, "rowspan": 1, "colspan": 1 } }, { "id": "p17.12.30", "order": 78, "type": "table_cell", "bbox": { "l": 222.96, "t": 479.92, "r": 256.08, "b": 466.28 }, "text": "3.63 m", "attrs": { "row": 4, "col": 1, "rowspan": 1, "colspan": 1 } }, { "id": "p17.12.31", "order": 79, "type": "table_cell", "bbox": { "l": 256.08, "t": 479.92, "r": 289.2, "b": 466.28 }, "text": "3.41 m", "attrs": { "row": 4, "col": 2, "rowspan": 1, "colspan": 1 } }, { "id": "p17.12.32", "order": 80, "type": "table_cell", "bbox": { "l": 289.2, "t": 479.92, "r": 322.32, "b": 466.28 }, "text": "3.78 m", "attrs": { "row": 4, "col": 3, "rowspan": 1, "colspan": 1 } }, { "id": "p17.12.33", "order": 81, "type": "table_cell", "bbox": { "l": 322.32, "t": 479.92, "r": 355.44, "b": 466.28 }, "text": "3.78 m", "attrs": { "row": 4, "col": 4, "rowspan": 1, "colspan": 1 } }, { "id": "p17.12.34", "order": 82, "type": "table_cell", "bbox": { "l": 355.44, "t": 479.92, "r": 388.56, "b": 466.28 }, "text": "3.41 m", "attrs": { "row": 4, "col": 5, "rowspan": 1, "colspan": 1 } }, { "id": "p17.12.35", "order": 83, "type": "table_cell", "bbox": { "l": 388.56, "t": 479.92, "r": 421.68, "b": 466.28 }, "text": "---", "attrs": { "row": 4, "col": 6, "rowspan": 1, "colspan": 1 } }, { "id": "p17.12.36", "order": 84, "type": "table_cell", "bbox": { "l": 189.84, "t": 466.28, "r": 222.96, "b": 452.64 }, "text": "¹³C ( δ)", "attrs": { "row": 5, "col": 0, "rowspan": 1, "colspan": 1 } }, { "id": "p17.12.37", "order": 85, "type": "table_cell", "bbox": { "l": 222.96, "t": 466.28, "r": 256.08, "b": 452.64 }, "text": "71.5", "attrs": { "row": 5, "col": 1, "rowspan": 1, "colspan": 1 } }, { "id": "p17.12.38", "order": 86, "type": "table_cell", "bbox": { "l": 256.08, "t": 466.28, "r": 289.2, "b": 452.64 }, "text": "74.4", "attrs": { "row": 5, "col": 2, "rowspan": 1, "colspan": 1 } }, { "id": "p17.12.39", "order": 87, "type": "table_cell", "bbox": { "l": 289.2, "t": 466.28, "r": 322.32, "b": 452.64 }, "text": "82.5", "attrs": { "row": 5, "col": 3, "rowspan": 1, "colspan": 1 } }, { "id": "p17.12.40", "order": 88, "type": "table_cell", "bbox": { "l": 322.32, "t": 466.28, "r": 355.44, "b": 452.64 }, "text": "82.7", "attrs": { "row": 5, "col": 4, "rowspan": 1, "colspan": 1 } }, { "id": "p17.12.41", "order": 89, "type": "table_cell", "bbox": { "l": 355.44, "t": 466.28, "r": 388.56, "b": 452.64 }, "text": "74.3", "attrs": { "row": 5, "col": 5, "rowspan": 1, "colspan": 1 } }, { "id": "p17.12.42", "order": 90, "type": "table_cell", "bbox": { "l": 388.56, "t": 466.28, "r": 421.68, "b": 452.64 }, "text": "105.3", "attrs": { "row": 5, "col": 6, "rowspan": 1, "colspan": 1 } } ] }, { "id": "p17.13", "order": 91, "type": "text", "bbox": { "l": 63.12, "t": 498, "r": 153.84, "b": 487.44 }, "text": "40. 34-epi-goniodon" }, { "id": "p17.14", "order": 92, "type": "text", "bbox": { "l": 63.84, "t": 451.92, "r": 534.24, "b": 405.84 }, "text": "White amorphous powder. Mp: 78–80°C. [α]D: +3.4° (c O.17, MeOH). IR (νmax, film, cm⁻¹): 3514, 2921, 2852, 1734, 1467. MS: EIMS m/z 595, 577, 559, 541, 523, 413, 395, 377, 359, 341, 343, 325, 307, 289, 271, 257, 239, 221, 157, 139, 121. NMR: ¹H NMR (500MHz, CDCl₃), ¹³C NMR (125MHz, CDCl₃). Derivatives: phenylhydrazone (¹H NMR), per-MTPA esters (¹H NMR), TMS (EIMS). Biological activities (μg/mL): HCT-81C50 <10. Source: Goniothalamus donnaiensis, roots. cis-goniodonin³¹ (reported as an epimeric pair) (C₃₅H₆1O₂. MW612)" }, { "id": "p17.15", "order": 93, "type": "formula", "bbox": { "l": 154.56, "t": 404.4, "r": 455.76, "b": 360.48 }, "text": "", "attrs": { "block_label": "image", "alt": "Skeletal structure of an annonaceous acetogenin-type butenolide with a tetrahydrofuran ring, hydroxyls at C4, C10, C15, C20,…", "source": "vision" } }, { "id": "p17.16", "order": 94, "type": "text", "bbox": { "l": 62.88, "t": 358.8, "r": 141.12, "b": 348.72 }, "text": "41. cis-goniodonin" }, { "id": "p17.17", "order": 95, "type": "table", "bbox": { "l": 189.84, "t": 349.92, "r": 421.44, "b": 266.16 }, "text": "", "attrs": { "block_label": "table", "n_rows": 6, "n_cols": 7, "integrity": { "skipped": "no_text_layer" } }, "children": [ { "id": "p17.17.1", "order": 96, "type": "table_cell", "bbox": { "l": 189.84, "t": 349.92, "r": 222.9257, "b": 335.96 }, "text": "Position", "attrs": { "row": 0, "col": 0, "rowspan": 1, "colspan": 1, "column_header": true, "header_source": "heuristic" } }, { "id": "p17.17.2", "order": 97, "type": "table_cell", "bbox": { "l": 222.9257, "t": 349.92, "r": 256.0114, "b": 335.96 }, "text": "10", "attrs": { "row": 0, "col": 1, "rowspan": 1, "colspan": 1, "column_header": true, "header_source": "heuristic" } }, { "id": "p17.17.3", "order": 98, "type": "table_cell", "bbox": { "l": 256.0114, "t": 349.92, "r": 289.0971, "b": 335.96 }, "text": "15", "attrs": { "row": 0, "col": 2, "rowspan": 1, "colspan": 1, "column_header": true, "header_source": "heuristic" } }, { "id": "p17.17.4", "order": 99, "type": "table_cell", "bbox": { "l": 289.0971, "t": 349.92, "r": 322.1829, "b": 335.96 }, "text": "16", "attrs": { "row": 0, "col": 3, "rowspan": 1, "colspan": 1, "column_header": true, "header_source": "heuristic" } }, { "id": "p17.17.5", "order": 100, "type": "table_cell", "bbox": { "l": 322.1829, "t": 349.92, "r": 355.2686, "b": 335.96 }, "text": "19", "attrs": { "row": 0, "col": 4, "rowspan": 1, "colspan": 1, "column_header": true, "header_source": "heuristic" } }, { "id": "p17.17.6", "order": 101, "type": "table_cell", "bbox": { "l": 355.2686, "t": 349.92, "r": 388.3543, "b": 335.96 }, "text": "20", "attrs": { "row": 0, "col": 5, "rowspan": 1, "colspan": 1, "column_header": true, "header_source": "heuristic" } }, { "id": "p17.17.7", "order": 102, "type": "table_cell", "bbox": { "l": 388.3543, "t": 349.92, "r": 421.44, "b": 335.96 }, "text": "34", "attrs": { "row": 0, "col": 6, "rowspan": 1, "colspan": 1, "column_header": true, "header_source": "heuristic" } }, { "id": "p17.17.8", "order": 103, "type": "table_cell", "bbox": { "l": 189.84, "t": 335.96, "r": 222.9257, "b": 322 }, "text": "¹H (δ)", "attrs": { "row": 1, "col": 0, "rowspan": 1, "colspan": 1 } }, { "id": "p17.17.9", "order": 104, "type": "table_cell", "bbox": { "l": 222.9257, "t": 335.96, "r": 256.0114, "b": 322 }, "text": "3.63 m", "attrs": { "row": 1, "col": 1, "rowspan": 1, "colspan": 1 } }, { "id": "p17.17.10", "order": 105, "type": "table_cell", "bbox": { "l": 256.0114, "t": 335.96, "r": 289.0971, "b": 322 }, "text": "3.41 m", "attrs": { "row": 1, "col": 2, "rowspan": 1, "colspan": 1 } }, { "id": "p17.17.11", "order": 106, "type": "table_cell", "bbox": { "l": 289.0971, "t": 335.96, "r": 322.1829, "b": 322 }, "text": "3.78 m", "attrs": { "row": 1, "col": 3, "rowspan": 1, "colspan": 1 } }, { "id": "p17.17.12", "order": 107, "type": "table_cell", "bbox": { "l": 322.1829, "t": 335.96, "r": 355.2686, "b": 322 }, "text": "3.78 m", "attrs": { "row": 1, "col": 4, "rowspan": 1, "colspan": 1 } }, { "id": "p17.17.13", "order": 108, "type": "table_cell", "bbox": { "l": 355.2686, "t": 335.96, "r": 388.3543, "b": 322 }, "text": "3.41 m", "attrs": { "row": 1, "col": 5, "rowspan": 1, "colspan": 1 } }, { "id": "p17.17.14", "order": 109, "type": "table_cell", "bbox": { "l": 388.3543, "t": 335.96, "r": 421.44, "b": 322 }, "text": "---", "attrs": { "row": 1, "col": 6, "rowspan": 1, "colspan": 1 } }, { "id": "p17.17.15", "order": 110, "type": "table_cell", "bbox": { "l": 189.84, "t": 322, "r": 222.9257, "b": 308.04 }, "text": "¹³C (δ)", "attrs": { "row": 2, "col": 0, "rowspan": 1, "colspan": 1 } }, { "id": "p17.17.16", "order": 111, "type": "table_cell", "bbox": { "l": 222.9257, "t": 322, "r": 256.0114, "b": 308.04 }, "text": "71.4", "attrs": { "row": 2, "col": 1, "rowspan": 1, "colspan": 1 } }, { "id": "p17.17.17", "order": 112, "type": "table_cell", "bbox": { "l": 256.0114, "t": 322, "r": 289.0971, "b": 308.04 }, "text": "74.5", "attrs": { "row": 2, "col": 2, "rowspan": 1, "colspan": 1 } }, { "id": "p17.17.18", "order": 113, "type": "table_cell", "bbox": { "l": 289.0971, "t": 322, "r": 322.1829, "b": 308.04 }, "text": "82.6", "attrs": { "row": 2, "col": 3, "rowspan": 1, "colspan": 1 } }, { "id": "p17.17.19", "order": 114, "type": "table_cell", "bbox": { "l": 322.1829, "t": 322, "r": 355.2686, "b": 308.04 }, "text": "82.6", "attrs": { "row": 2, "col": 4, "rowspan": 1, "colspan": 1 } }, { "id": "p17.17.20", "order": 115, "type": "table_cell", "bbox": { "l": 355.2686, "t": 322, "r": 388.3543, "b": 308.04 }, "text": "74.2", "attrs": { "row": 2, "col": 5, "rowspan": 1, "colspan": 1 } }, { "id": "p17.17.21", "order": 116, "type": "table_cell", "bbox": { "l": 388.3543, "t": 322, "r": 421.44, "b": 308.04 }, "text": "105.0", "attrs": { "row": 2, "col": 6, "rowspan": 1, "colspan": 1 } }, { "id": "p17.17.22", "order": 117, "type": "table_cell", "bbox": { "l": 189.84, "t": 308.04, "r": 222.9257, "b": 294.08 }, "text": "Position", "attrs": { "row": 3, "col": 0, "rowspan": 1, "colspan": 1 } }, { "id": "p17.17.23", "order": 118, "type": "table_cell", "bbox": { "l": 222.9257, "t": 308.04, "r": 256.0114, "b": 294.08 }, "text": "10", "attrs": { "row": 3, "col": 1, "rowspan": 1, "colspan": 1 } }, { "id": "p17.17.24", "order": 119, "type": "table_cell", "bbox": { "l": 256.0114, "t": 308.04, "r": 289.0971, "b": 294.08 }, "text": "15", "attrs": { "row": 3, "col": 2, "rowspan": 1, "colspan": 1 } }, { "id": "p17.17.25", "order": 120, "type": "table_cell", "bbox": { "l": 289.0971, "t": 308.04, "r": 322.1829, "b": 294.08 }, "text": "16", "attrs": { "row": 3, "col": 3, "rowspan": 1, "colspan": 1 } }, { "id": "p17.17.26", "order": 121, "type": "table_cell", "bbox": { "l": 322.1829, "t": 308.04, "r": 355.2686, "b": 294.08 }, "text": "19", "attrs": { "row": 3, "col": 4, "rowspan": 1, "colspan": 1 } }, { "id": "p17.17.27", "order": 122, "type": "table_cell", "bbox": { "l": 355.2686, "t": 308.04, "r": 388.3543, "b": 294.08 }, "text": "20", "attrs": { "row": 3, "col": 5, "rowspan": 1, "colspan": 1 } }, { "id": "p17.17.28", "order": 123, "type": "table_cell", "bbox": { "l": 388.3543, "t": 308.04, "r": 421.44, "b": 294.08 }, "text": "34", "attrs": { "row": 3, "col": 6, "rowspan": 1, "colspan": 1 } }, { "id": "p17.17.29", "order": 124, "type": "table_cell", "bbox": { "l": 189.84, "t": 294.08, "r": 222.9257, "b": 280.12 }, "text": "¹H (δ)", "attrs": { "row": 4, "col": 0, "rowspan": 1, "colspan": 1 } }, { "id": "p17.17.30", "order": 125, "type": "table_cell", "bbox": { "l": 222.9257, "t": 294.08, "r": 256.0114, "b": 280.12 }, "text": "3.63 m", "attrs": { "row": 4, "col": 1, "rowspan": 1, "colspan": 1 } }, { "id": "p17.17.31", "order": 126, "type": "table_cell", "bbox": { "l": 256.0114, "t": 294.08, "r": 289.0971, "b": 280.12 }, "text": "3.41 m", "attrs": { "row": 4, "col": 2, "rowspan": 1, "colspan": 1 } }, { "id": "p17.17.32", "order": 127, "type": "table_cell", "bbox": { "l": 289.0971, "t": 294.08, "r": 322.1829, "b": 280.12 }, "text": "3.78 m", "attrs": { "row": 4, "col": 3, "rowspan": 1, "colspan": 1 } }, { "id": "p17.17.33", "order": 128, "type": "table_cell", "bbox": { "l": 322.1829, "t": 294.08, "r": 355.2686, "b": 280.12 }, "text": "3.78 m", "attrs": { "row": 4, "col": 4, "rowspan": 1, "colspan": 1 } }, { "id": "p17.17.34", "order": 129, "type": "table_cell", "bbox": { "l": 355.2686, "t": 294.08, "r": 388.3543, "b": 280.12 }, "text": "3.41 m", "attrs": { "row": 4, "col": 5, "rowspan": 1, "colspan": 1 } }, { "id": "p17.17.35", "order": 130, "type": "table_cell", "bbox": { "l": 388.3543, "t": 294.08, "r": 421.44, "b": 280.12 }, "text": "---", "attrs": { "row": 4, "col": 6, "rowspan": 1, "colspan": 1 } }, { "id": "p17.17.36", "order": 131, "type": "table_cell", "bbox": { "l": 189.84, "t": 280.12, "r": 222.9257, "b": 266.16 }, "text": "¹³C (δ)", "attrs": { "row": 5, "col": 0, "rowspan": 1, "colspan": 1 } }, { "id": "p17.17.37", "order": 132, "type": "table_cell", "bbox": { "l": 222.9257, "t": 280.12, "r": 256.0114, "b": 266.16 }, "text": "71.4", "attrs": { "row": 5, "col": 1, "rowspan": 1, "colspan": 1 } }, { "id": "p17.17.38", "order": 133, "type": "table_cell", "bbox": { "l": 256.0114, "t": 280.12, "r": 289.0971, "b": 266.16 }, "text": "74.5", "attrs": { "row": 5, "col": 2, "rowspan": 1, "colspan": 1 } }, { "id": "p17.17.39", "order": 134, "type": "table_cell", "bbox": { "l": 289.0971, "t": 280.12, "r": 322.1829, "b": 266.16 }, "text": "82.6", "attrs": { "row": 5, "col": 3, "rowspan": 1, "colspan": 1 } }, { "id": "p17.17.40", "order": 135, "type": "table_cell", "bbox": { "l": 322.1829, "t": 280.12, "r": 355.2686, "b": 266.16 }, "text": "82.6", "attrs": { "row": 5, "col": 4, "rowspan": 1, "colspan": 1 } }, { "id": "p17.17.41", "order": 136, "type": "table_cell", "bbox": { "l": 355.2686, "t": 280.12, "r": 388.3543, "b": 266.16 }, "text": "74.2", "attrs": { "row": 5, "col": 5, "rowspan": 1, "colspan": 1 } }, { "id": "p17.17.42", "order": 137, "type": "table_cell", "bbox": { "l": 388.3543, "t": 280.12, "r": 421.44, "b": 266.16 }, "text": "105.3", "attrs": { "row": 5, "col": 6, "rowspan": 1, "colspan": 1 } } ] }, { "id": "p17.18", "order": 138, "type": "text", "bbox": { "l": 62.64, "t": 312, "r": 168, "b": 302.16 }, "text": "42. 34-epi-cis-goniodon" }, { "id": "p17.19", "order": 139, "type": "text", "bbox": { "l": 65.04, "t": 265.68, "r": 546.72, "b": 221.28 }, "text": "White amorphous powder. Mp: 80–82°C. [α]D: +3.8° (c O.I.Q, MeOH). IR (νmax, film, cm⁻¹): 3413, 2920, 2851, 1735, 1465. MS: EIMS m/z 595, 577, 559, 541, 523, 413, 395, 377, 359, 341, 343, 325, 307, 289, 271, 257, 239, 221, 157, 139, 121. NMR: ¹H NMR (500MHz, CDCl₃), ¹³C NMR (125MHz, CDCl₃). Derivatives: phenylhydrazone (¹H NMR), per-MTPA esters (¹H NMR), TMS (EIMS). Biological activities (μg/mL): HCT-8IC₅₀ <10. Source: Goniothalamus donnaiensis, roots. isomurisolenin¹¹⁴ (reported as cis and trans mixture) (C₃₅H₆₂O₆, MW578)" }, { "id": "p17.20", "order": 140, "type": "formula", "bbox": { "l": 153.84, "t": 217.2, "r": 456.24, "b": 173.76 }, "text": "", "attrs": { "block_label": "image", "alt": "Skeletal structure of an acetogenin-type lactone with a tetrahydrofuran ring, two hydroxyls at C15 and C20, a cis/trans C11…", "source": "vision" } }, { "id": "p17.21", "order": 141, "type": "text", "bbox": { "l": 62.88, "t": 170.88, "r": 176.64, "b": 161.28 }, "text": "43. (2,4-cis)-isomurisolenin" }, { "id": "p17.22", "order": 142, "type": "table", "bbox": { "l": 62.4, "t": 163.92, "r": 425.76, "b": 81.36 }, "text": "", "attrs": { "block_label": "table", "n_rows": 6, "n_cols": 8, "integrity": { "cells_checked": 43, "cells_flagged": 43, "flags": [ { "row": 0, "col": 0, "coverage": 0.5, "text": "44. (2,4-trans)-isomurisolenin" }, { "row": 0, "col": 1, "coverage": 0, "text": "Position" }, { "row": 0, "col": 2, "coverage": 0, "text": "11" }, { "row": 0, "col": 3, "coverage": 0, "text": "12" }, { "row": 0, "col": 4, "coverage": 0, "text": "15" }, { "row": 0, "col": 5, "coverage": 0, "text": "16" }, { "row": 0, "col": 6, "coverage": 0, "text": "19" }, { "row": 0, "col": 7, "coverage": 0, "text": "20" }, { "row": 1, "col": 0, "coverage": 0, "text": "¹H ( δ)" }, { "row": 1, "col": 1, "coverage": 0, "text": "5.36" }, { "row": 1, "col": 2, "coverage": 0, "text": "5.38" }, { "row": 1, "col": 3, "coverage": 0, "text": "3.40 m" } ] } }, "children": [ { "id": "p17.22.1", "order": 143, "type": "table_cell", "bbox": { "l": 62.4, "t": 163.92, "r": 107.82, "b": 81.36 }, "text": "44. (2,4-trans)-isomurisolenin", "attrs": { "row": 0, "col": 0, "rowspan": 6, "colspan": 1, "column_header": true, "header_source": "heuristic" } }, { "id": "p17.22.2", "order": 144, "type": "table_cell", "bbox": { "l": 107.82, "t": 163.92, "r": 153.24, "b": 150.16 }, "text": "Position", "attrs": { "row": 0, "col": 1, "rowspan": 1, "colspan": 1, "column_header": true, "header_source": "heuristic" } }, { "id": "p17.22.3", "order": 145, "type": "table_cell", "bbox": { "l": 153.24, "t": 163.92, "r": 198.66, "b": 150.16 }, "text": "11", "attrs": { "row": 0, "col": 2, "rowspan": 1, "colspan": 1, "column_header": true, "header_source": "heuristic" } }, { "id": "p17.22.4", "order": 146, "type": "table_cell", "bbox": { "l": 198.66, "t": 163.92, "r": 244.08, "b": 150.16 }, "text": "12", "attrs": { "row": 0, "col": 3, "rowspan": 1, "colspan": 1, "column_header": true, "header_source": "heuristic" } }, { "id": "p17.22.5", "order": 147, "type": "table_cell", "bbox": { "l": 244.08, "t": 163.92, "r": 289.5, "b": 150.16 }, "text": "15", "attrs": { "row": 0, "col": 4, "rowspan": 1, "colspan": 1, "column_header": true, "header_source": "heuristic" } }, { "id": "p17.22.6", "order": 148, "type": "table_cell", "bbox": { "l": 289.5, "t": 163.92, "r": 334.92, "b": 150.16 }, "text": "16", "attrs": { "row": 0, "col": 5, "rowspan": 1, "colspan": 1, "column_header": true, "header_source": "heuristic" } }, { "id": "p17.22.7", "order": 149, "type": "table_cell", "bbox": { "l": 334.92, "t": 163.92, "r": 380.34, "b": 150.16 }, "text": "19", "attrs": { "row": 0, "col": 6, "rowspan": 1, "colspan": 1, "column_header": true, "header_source": "heuristic" } }, { "id": "p17.22.8", "order": 150, "type": "table_cell", "bbox": { "l": 380.34, "t": 163.92, "r": 425.76, "b": 150.16 }, "text": "20", "attrs": { "row": 0, "col": 7, "rowspan": 1, "colspan": 1, "column_header": true, "header_source": "heuristic" } }, { "id": "p17.22.9", "order": 151, "type": "table_cell", "bbox": { "l": 107.82, "t": 150.16, "r": 153.24, "b": 136.4 }, "text": "¹H ( δ)", "attrs": { "row": 1, "col": 0, "rowspan": 1, "colspan": 1 } }, { "id": "p17.22.10", "order": 152, "type": "table_cell", "bbox": { "l": 153.24, "t": 150.16, "r": 198.66, "b": 136.4 }, "text": "5.36", "attrs": { "row": 1, "col": 1, "rowspan": 1, "colspan": 1 } }, { "id": "p17.22.11", "order": 153, "type": "table_cell", "bbox": { "l": 198.66, "t": 150.16, "r": 244.08, "b": 136.4 }, "text": "5.38", "attrs": { "row": 1, "col": 2, "rowspan": 1, "colspan": 1 } }, { "id": "p17.22.12", "order": 154, "type": "table_cell", "bbox": { "l": 244.08, "t": 150.16, "r": 289.5, "b": 136.4 }, "text": "3.40 m", "attrs": { "row": 1, "col": 3, "rowspan": 1, "colspan": 1 } }, { "id": "p17.22.13", "order": 155, "type": "table_cell", "bbox": { "l": 289.5, "t": 150.16, "r": 334.92, "b": 136.4 }, "text": "3.80 m", "attrs": { "row": 1, "col": 4, "rowspan": 1, "colspan": 1 } }, { "id": "p17.22.14", "order": 156, "type": "table_cell", "bbox": { "l": 334.92, "t": 150.16, "r": 380.34, "b": 136.4 }, "text": "3.80 m", "attrs": { "row": 1, "col": 5, "rowspan": 1, "colspan": 1 } }, { "id": "p17.22.15", "order": 157, "type": "table_cell", "bbox": { "l": 380.34, "t": 150.16, "r": 425.76, "b": 136.4 }, "text": "3.40 m", "attrs": { "row": 1, "col": 6, "rowspan": 1, "colspan": 1 } }, { "id": "p17.22.16", "order": 158, "type": "table_cell", "bbox": { "l": 107.82, "t": 136.4, "r": 153.24, "b": 122.64 }, "text": "¹³C ( δ)", "attrs": { "row": 2, "col": 0, "rowspan": 1, "colspan": 1 } }, { "id": "p17.22.17", "order": 159, "type": "table_cell", "bbox": { "l": 153.24, "t": 136.4, "r": 198.66, "b": 122.64 }, "text": "130.7", "attrs": { "row": 2, "col": 1, "rowspan": 1, "colspan": 1 } }, { "id": "p17.22.18", "order": 160, "type": "table_cell", "bbox": { "l": 198.66, "t": 136.4, "r": 244.08, "b": 122.64 }, "text": "128.9", "attrs": { "row": 2, "col": 2, "rowspan": 1, "colspan": 1 } }, { "id": "p17.22.19", "order": 161, "type": "table_cell", "bbox": { "l": 244.08, "t": 136.4, "r": 289.5, "b": 122.64 }, "text": "74.0", "attrs": { "row": 2, "col": 3, "rowspan": 1, "colspan": 1 } }, { "id": "p17.22.20", "order": 162, "type": "table_cell", "bbox": { "l": 289.5, "t": 136.4, "r": 334.92, "b": 122.64 }, "text": "82.6", "attrs": { "row": 2, "col": 4, "rowspan": 1, "colspan": 1 } }, { "id": "p17.22.21", "order": 163, "type": "table_cell", "bbox": { "l": 334.92, "t": 136.4, "r": 380.34, "b": 122.64 }, "text": "82.5", "attrs": { "row": 2, "col": 5, "rowspan": 1, "colspan": 1 } }, { "id": "p17.22.22", "order": 164, "type": "table_cell", "bbox": { "l": 380.34, "t": 136.4, "r": 425.76, "b": 122.64 }, "text": "74.0", "attrs": { "row": 2, "col": 6, "rowspan": 1, "colspan": 1 } }, { "id": "p17.22.23", "order": 165, "type": "table_cell", "bbox": { "l": 107.82, "t": 122.64, "r": 153.24, "b": 108.88 }, "text": "Position", "attrs": { "row": 3, "col": 0, "rowspan": 1, "colspan": 1 } }, { "id": "p17.22.24", "order": 166, "type": "table_cell", "bbox": { "l": 153.24, "t": 122.64, "r": 198.66, "b": 108.88 }, "text": "11", "attrs": { "row": 3, "col": 1, "rowspan": 1, "colspan": 1 } }, { "id": "p17.22.25", "order": 167, "type": "table_cell", "bbox": { "l": 198.66, "t": 122.64, "r": 244.08, "b": 108.88 }, "text": "12", "attrs": { "row": 3, "col": 2, "rowspan": 1, "colspan": 1 } }, { "id": "p17.22.26", "order": 168, "type": "table_cell", "bbox": { "l": 244.08, "t": 122.64, "r": 289.5, "b": 108.88 }, "text": "15", "attrs": { "row": 3, "col": 3, "rowspan": 1, "colspan": 1 } }, { "id": "p17.22.27", "order": 169, "type": "table_cell", "bbox": { "l": 289.5, "t": 122.64, "r": 334.92, "b": 108.88 }, "text": "16", "attrs": { "row": 3, "col": 4, "rowspan": 1, "colspan": 1 } }, { "id": "p17.22.28", "order": 170, "type": "table_cell", "bbox": { "l": 334.92, "t": 122.64, "r": 380.34, "b": 108.88 }, "text": "19", "attrs": { "row": 3, "col": 5, "rowspan": 1, "colspan": 1 } }, { "id": "p17.22.29", "order": 171, "type": "table_cell", "bbox": { "l": 380.34, "t": 122.64, "r": 425.76, "b": 108.88 }, "text": "20", "attrs": { "row": 3, "col": 6, "rowspan": 1, "colspan": 1 } }, { "id": "p17.22.30", "order": 172, "type": "table_cell", "bbox": { "l": 107.82, "t": 108.88, "r": 153.24, "b": 95.12 }, "text": "¹H ( δ)", "attrs": { "row": 4, "col": 0, "rowspan": 1, "colspan": 1 } }, { "id": "p17.22.31", "order": 173, "type": "table_cell", "bbox": { "l": 153.24, "t": 108.88, "r": 198.66, "b": 95.12 }, "text": "5.36", "attrs": { "row": 4, "col": 1, "rowspan": 1, "colspan": 1 } }, { "id": "p17.22.32", "order": 174, "type": "table_cell", "bbox": { "l": 198.66, "t": 108.88, "r": 244.08, "b": 95.12 }, "text": "5.38", "attrs": { "row": 4, "col": 2, "rowspan": 1, "colspan": 1 } }, { "id": "p17.22.33", "order": 175, "type": "table_cell", "bbox": { "l": 244.08, "t": 108.88, "r": 289.5, "b": 95.12 }, "text": "3.40 m", "attrs": { "row": 4, "col": 3, "rowspan": 1, "colspan": 1 } }, { "id": "p17.22.34", "order": 176, "type": "table_cell", "bbox": { "l": 289.5, "t": 108.88, "r": 334.92, "b": 95.12 }, "text": "3.80 m", "attrs": { "row": 4, "col": 4, "rowspan": 1, "colspan": 1 } }, { "id": "p17.22.35", "order": 177, "type": "table_cell", "bbox": { "l": 334.92, "t": 108.88, "r": 380.34, "b": 95.12 }, "text": "3.80 m", "attrs": { "row": 4, "col": 5, "rowspan": 1, "colspan": 1 } }, { "id": "p17.22.36", "order": 178, "type": "table_cell", "bbox": { "l": 380.34, "t": 108.88, "r": 425.76, "b": 95.12 }, "text": "3.40 m", "attrs": { "row": 4, "col": 6, "rowspan": 1, "colspan": 1 } }, { "id": "p17.22.37", "order": 179, "type": "table_cell", "bbox": { "l": 107.82, "t": 95.12, "r": 153.24, "b": 81.36 }, "text": "¹³C ( δ)", "attrs": { "row": 5, "col": 0, "rowspan": 1, "colspan": 1 } }, { "id": "p17.22.38", "order": 180, "type": "table_cell", "bbox": { "l": 153.24, "t": 95.12, "r": 198.66, "b": 81.36 }, "text": "130.7", "attrs": { "row": 5, "col": 1, "rowspan": 1, "colspan": 1 } }, { "id": "p17.22.39", "order": 181, "type": "table_cell", "bbox": { "l": 198.66, "t": 95.12, "r": 244.08, "b": 81.36 }, "text": "128.9", "attrs": { "row": 5, "col": 2, "rowspan": 1, "colspan": 1 } }, { "id": "p17.22.40", "order": 182, "type": "table_cell", "bbox": { "l": 244.08, "t": 95.12, "r": 289.5, "b": 81.36 }, "text": "74.0", "attrs": { "row": 5, "col": 3, "rowspan": 1, "colspan": 1 } }, { "id": "p17.22.41", "order": 183, "type": "table_cell", "bbox": { "l": 289.5, "t": 95.12, "r": 334.92, "b": 81.36 }, "text": "82.6", "attrs": { "row": 5, "col": 4, "rowspan": 1, "colspan": 1 } }, { "id": "p17.22.42", "order": 184, "type": "table_cell", "bbox": { "l": 334.92, "t": 95.12, "r": 380.34, "b": 81.36 }, "text": "82.5", "attrs": { "row": 5, "col": 5, "rowspan": 1, "colspan": 1 } }, { "id": "p17.22.43", "order": 185, "type": "table_cell", "bbox": { "l": 380.34, "t": 95.12, "r": 425.76, "b": 81.36 }, "text": "74.0", "attrs": { "row": 5, "col": 6, "rowspan": 1, "colspan": 1 } } ] }, { "id": "p17.23", "order": 186, "type": "footnote", "bbox": { "l": 63.12, "t": 78.96, "r": 518.16, "b": 42.48 }, "text": "White waxy solid.[p17.23.1]: +32.9° (c 0.31, CHCl_{3}). IR ([p17.23.2], film, cm^{-1}): 3500, 2910, 2860, 1760, 1710, 1460, 1250, 1050, 800. MS: EIMS m/z 391, 379, 373, 361, 291, 265, 211, 141. NMR: ^1H NMR (400 MHz, CDCl_{3}), ^13C NMR (100 MHz, CDCl_{3}). Biological activities ( [p17.23.3]g/mL): Hep. 2, 2, 2, 15 ED_{50} 1.4[p17.23.4] 10^{-1}, Hep G2 ED_{50} 4.7[p17.23.5] 10^{-2}, KB ED_{50} 1, CCM2 ED_{50} 8.5[p17.23.6] 10^{-2}. Source: Annona reticulata, seeds.", "attrs": { "block_label": "vision_footnote" }, "children": [ { "id": "p17.23.1", "order": 187, "type": "formula", "bbox": { "l": 63.12, "t": 78.96, "r": 518.16, "b": 42.48 }, "text": "[\\alpha]_{D}", "attrs": { "latex": "[\\alpha]_{D}", "inline": true, "text_offset": 17, "text_span": 10, "bbox_estimated": true, "notation": "latex", "alt": "alpha sub D", "mathml": "[α]D" } }, { "id": "p17.23.2", "order": 188, "type": "formula", "bbox": { "l": 63.12, "t": 78.96, "r": 518.16, "b": 42.48 }, "text": "\\text{White waxy solid. }[\\alpha]_D\\text{: }+32.9^\\circ\\ (c\\ 0.31, \\text{CHCl}_3)\\text{. IR }(\\nu_{max}\\text{, film, cm}^{-1})\\text{: }3500, 2910, 2860, 1760, 1710, 1460, 1250, 1050, 800.\\ \\text{MS: EIMS } m/z\\ 391, 379, 373, 361, 291, 265, 211, 141.\\ \\text{NMR: }{}^{1}\\text{H NMR (400 MHz, CDCl}_3\\text{), }{}^{13}\\text{C NMR (100 MHz, CDCl}_3\\text{).}\\ \\text{Biological activities }(\\mu\\text{g/mL})\\text{: Hep. 2, 2, 15 ED}_{50}\\ 1.4\\times10^{-1}\\text{, Hep G2 ED}_{50}\\ 4.7\\times10^{-2}\\text{, KB ED}_{50}\\ 1\\text{, CCM2 ED}_{50}\\ 8.5\\times10^{-2}.\\ \\text{Source: }\\textit{Annona reticulata}\\text{, seeds.}", "attrs": { "latex": "\\text{White waxy solid. }[\\alpha]_D\\text{: }+32.9^\\circ\\ (c\\ 0.31, \\text{CHCl}_3)\\text{. IR }(\\nu_{max}\\text{, film, cm}^{-1})\\text{: }3500, 2910, 2860, 1760, 1710, 1460, 1250, 1050, 800.\\ \\text{MS: EIMS } m/z\\ 391, 379, 373, 361, 291, 265, 211, 141.\\ \\text{NMR: }{}^{1}\\text{H NMR (400 MHz, CDCl}_3\\text{), }{}^{13}\\text{C NMR (100 MHz, CDCl}_3\\text{).}\\ \\text{Biological activities }(\\mu\\text{g/mL})\\text{: Hep. 2, 2, 15 ED}_{50}\\ 1.4\\times10^{-1}\\text{, Hep G2 ED}_{50}\\ 4.7\\times10^{-2}\\text{, KB ED}_{50}\\ 1\\text{, CCM2 ED}_{50}\\ 8.5\\times10^{-2}.\\ \\text{Source: }\\textit{Annona reticulata}\\text{, seeds.}", "inline": true, "text_offset": 60, "text_span": 10, "bbox_estimated": true, "notation": "latex", "alt": "White waxy solid. alpha sub D : plus 32.9 to the power of circ of c 0.31, CHCl sub 3 . IR of nu sub max, film, cm to the power of minus 1 : 3500, 2910, 2860, 1760, 1710, 1460, 1250, 1050, 800. MS: EIMS m over z 391, 379, 373, 361, 291, 265, 211, 141. NMR: to the power of 1 H NMR of 400 MHz, CDCl sub 3, to the power of 13 C NMR of 100 MHz, CDCl sub 3 . Biological activities of mu g over mL : Hep. 2, 2, 15 ED sub 50 1.4 times 10 to the power of minus 1, Hep G2 ED sub 50 4.7 times 10 to the power of minus 2, KB ED sub 50 1, CCM2 ED sub 50 8.5 times 10 to the power of minus 2 . Source: textit Annona reticulata, seeds.", "mathml": "White waxy solid. [α]D: +32.9∘ (c 0.31,CHCl3). IR (νmax, film, cm−1): 3500,2910,2860,1760,1710,1460,1250,1050,800. MS: EIMS m/z 391,379,373,361,291,265,211,141. NMR: 1H NMR (400 MHz, CDCl3), 13C NMR (100 MHz, CDCl3). Biological activities (μg/mL): Hep. 2, 2, 15 ED50 1.4×10−1, Hep G2 ED50 4.7×10−2, KB ED50 1, CCM2 ED50 8.5×10−2. Source: Annona reticulata, seeds." } }, { "id": "p17.23.3", "order": 189, "type": "text", "bbox": { "l": 63.12, "t": 78.96, "r": 518.16, "b": 42.48 }, "text": "μ", "attrs": { "inline": true, "text_offset": 282, "text_span": 10, "bbox_estimated": true } }, { "id": "p17.23.4", "order": 190, "type": "text", "bbox": { "l": 63.12, "t": 78.96, "r": 518.16, "b": 42.48 }, "text": "×", "attrs": { "inline": true, "text_offset": 327, "text_span": 10, "bbox_estimated": true } }, { "id": "p17.23.5", "order": 191, "type": "text", "bbox": { "l": 63.12, "t": 78.96, "r": 518.16, "b": 42.48 }, "text": "×", "attrs": { "inline": true, "text_offset": 365, "text_span": 10, "bbox_estimated": true } }, { "id": "p17.23.6", "order": 192, "type": "text", "bbox": { "l": 63.12, "t": 78.96, "r": 518.16, "b": 42.48 }, "text": "×", "attrs": { "inline": true, "text_offset": 415, "text_span": 10, "bbox_estimated": true } } ] } ], "excluded_furniture": { "first": [], "last": [] } }